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Chemical Bonding: Ionic and Covalent

Topic: Chemical Bonding

Atoms combine to achieve a stable (octet) electronic configuration — usually a full outer shell of 8 electrons. The two main types of chemical bonding are ionic and covalent.

Ionic Bonding

An ionic bond is formed when one atom transfers electrons to another atom, producing oppositely charged ions that attract each other.

  • Metals (few outer electrons) lose electrons to form positive ions (cations).
  • Non-metals (nearly full outer shells) gain electrons to form negative ions (anions).
Example: In sodium chloride (NaCl), sodium loses 1 electron to become Na⁺, and chlorine gains it to become Cl⁻. The Na⁺ and Cl⁻ ions attract to form NaCl.

Covalent Bonding

A covalent bond is formed when two atoms share pairs of electrons. This occurs between non-metals.

  • A single bond shares one pair of electrons (e.g. H₂, Cl₂).
  • A double bond shares two pairs (e.g. O₂).
  • A triple bond shares three pairs (e.g. N₂).

Comparing Ionic and Covalent Compounds

Property Ionic compounds Covalent compounds
Melting/boiling point High Low
Conduct electricity? Yes, when molten or in solution No (except some in solution)
State at room temp Usually solid Liquid, gas or soft solid
Bond formed by Electron transfer Electron sharing

Metallic Bonding

In metals, atoms release their outer electrons into a “sea” of free (delocalised) electrons. This explains why metals are good conductors of electricity and heat and can be shaped (malleable).

Summary

Atoms bond to gain a stable outer shell. Ionic bonds involve electron transfer (metal + non-metal), while covalent bonds involve electron sharing (non-metal + non-metal). Their different bonding explains their different physical properties.

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