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Atomic Structure

Topic: Atomic Structure

All matter is made of atoms. An atom is the smallest particle of an element that can take part in a chemical reaction. It consists of a central nucleus surrounded by electrons.

Sub-atomic Particles

Particle Symbol Charge Relative mass Location
Proton p +1 1 Nucleus
Neutron n 0 1 Nucleus
Electron e⁻ −1 1/1840 (negligible) Shells (orbits)

Atomic Number and Mass Number

  • Atomic number (Z) = number of protons (also equals the number of electrons in a neutral atom). It identifies the element.
  • Mass number (A) = number of protons + neutrons.
  • Number of neutrons = A − Z.
Example: Sodium has Z = 11 and A = 23. So it has 11 protons, 11 electrons and 23 − 11 = 12 neutrons.

Isotopes

Isotopes are atoms of the same element with the same atomic number but different mass numbers (different numbers of neutrons). Example: carbon-12 and carbon-14.

Electronic Configuration

Electrons are arranged in shells around the nucleus. The shells fill in the order 2, 8, 8, 18…

  • Sodium (11 electrons): 2, 8, 1
  • Oxygen (8 electrons): 2, 6
  • Calcium (20 electrons): 2, 8, 8, 2
Na Sodium atom: 11 protons in nucleus, electrons in shells 2, 8, 1
Structure of a sodium atom (electronic configuration 2, 8, 1).

Summary

An atom has protons and neutrons in its nucleus and electrons in shells around it. Atomic number = protons, mass number = protons + neutrons. Isotopes differ in neutron number, and electronic configuration follows the 2, 8, 8… pattern.

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