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Rates of Reaction

Topic: Rates Of Reaction

The rate of reaction is the speed at which reactants are converted into products. It is measured as the change in concentration of a reactant or product per unit time.

Factors Affecting the Rate of Reaction

  • Concentration: higher concentration of reactants → more particles → faster reaction.
  • Temperature: higher temperature → particles move faster and collide more often with more energy → faster reaction.
  • Surface area: smaller particle size (larger surface area) → faster reaction.
  • Pressure (for gases): higher pressure → faster reaction.
  • Catalyst: speeds up the reaction without being used up.

Collision Theory

For a reaction to occur, particles must collide with enough energy (the activation energy) and with the correct orientation. Anything that increases the frequency of effective collisions increases the reaction rate.

Catalysts

A catalyst increases the rate of a reaction by lowering the activation energy, without being consumed. Biological catalysts are called enzymes.

Example: Manganese(IV) oxide catalyses the decomposition of hydrogen peroxide; enzymes in the body speed up digestion.

Summary

The rate of reaction increases with higher concentration, temperature, surface area and pressure, and with the use of a catalyst. Collision theory explains these effects through the frequency and energy of particle collisions.

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